3/10/2024 0 Comments Shankar quantum solution 18.5.2![]() Ozone-Free Synthesis of Ozonides: Assembling Bicyclic Structures from 1,5-Diketones and Hydrogen Peroxide. Yaremenko, Gabriel dos Passos Gomes, Peter S. This article is cited by 15 publications. Compared to ozonides previously synthesized in our laboratory, the new ozonides described herein present improved plant growth regulatory activity. The most active cycloadducts and ozonides were also evaluated against the weed species Ipomoea grandifolia and Brachiaria decumbens, and the results are discussed. The effect of these ozonides and their corresponding precursor cycloadducts upon radicle growth of both Sorghum bicolor and Cucumis sativus was evaluated at 5.0 × 10 −4 mol L −1. Ozonides were investigated by quantum mechanics at the B3LYP/6-31+G* level to study structural features including close contacts which may be responsible for enhancing ozonide stability. ![]() ![]() Dipolar cycloaddition of ozone to the adducts afforded the corresponding secondary ozonides (i.e., 1,2,4-trioxolanes) in variable yields. Similar methodology was used to prepare two additional cycloadducts using menthofuran and two homologous aliphatic dibromoketones. The iron oxyallyl carbocation generated from 2,7-dibromocycloheptanone was induced to undergo cycloaddition reactions with various furans, affording a series of 12-oxatricyclo-dodec-3-en-11-one adducts. ![]()
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